Safety manual

Contents Table 1. Organic Solvents Table 2. Specified Chemical Substances Table 3. Poisonous Substances Attached Table 3: Specified poisonous substances Table 4. Deleterious Substances Table 5. Narcotics (Narcotics and Psychoactive Drugs Control Law) Table 6. Psychoactive drugs (Narcotics and Psychoactive Drugs Control Law) Table 7. Stimulants and Ingredients of Stimulants (Stimulants Control Law) Table 8. Hazardous Substances Table 9. Gases with Special Components or a Special Component Faculty and Graduate School of Science, The University of Tokyo Table 1. Organic Solvents
(Ordinance on Prevention of Organic Solvent Poisoning) Note: In the case of a mixture, the ordinance applies if the mixture contains more than 5% by weight of any one of the following organic solvents. Class 1 Organic Solvents (7 substances)
(Halogenated hydrocarbons)
1 Chloroform
2 Carbon
3 1,2-Dichloroethane 4 1,2-Dichloroethylene 5 Trichloroethylene 6 1,1,2,2-Tetrachloroethane Class 2 Organic Solvents (40 substances)
(Hydrocarbons)
8
Dichloromethane (otherwise known as Methylene chloride) 13 1,1,1-Trichloroethane 14 Tetrachloroethylene Methanol (otherwise known as Methyl alcohol) Isopentyl alcohol (otherwise known as Isoamyl alcohol) Ethylene glycol monomethyl ether (otherwise known as Methyl cellosolve) Ethylene glycol monoethyl ether (otherwise known as Cellosolve) Ethylene glycol monoethyl ether acetate (otherwise known as Cellosolve acetate) Ethylene glycol monobutyl ether (otherwise known as Butyl cellosolve) Pentyl acetate (otherwise known as Amyl acetate) Isopentyl acetate (otherwise known as Isoamyl acetate) Class 3 Organic Solvents (7 substances)
48 Gasoline
49 Petroleum
Table 2. Specified Chemical Substances
(Ordinance on Prevention of Hazards due to Specified Chemical Substances) Note 1: Substances indicated by an asterisk are special chemical substances (22 substances). Note 2: In the case of a mixture, the ordinance applies if the mixture contains more than the concentration Type 1 Substances (7 substances)
Polychlorinated biphenyl (1 w/w%)
Dichlorobenzidine and its salts* (1 w/w%)
α-Naphthylamine and its salts* (1 w/w%)
o-Tolidine and its salts* (1 w/w%)
Dianisidine and its salts* (1 w/w%)
Benzotrichloride* (0.5 w/w%)
Beryllium and its compounds* (1 w/w%, but in case of its alloy, 3 w/w%)
Type 2 Substances (37 substances)
Hydrogen cyanide (1 w/w%) Methyl bromide (1 w/w%) Acrylamide (1 w/w%) Acrylonitrile (1 w/w%) Chlorine (1 w/w%) Tolylene diisocyanate (1 w/w%) p-Chloronitrobenzene (5 w/w%) Hydrogen fluoride (5 w/w%) Methyl iodide (1 w/w%) Hydrogen sulfide (1 w/w%) Dimethyl sulfate (1 w/w%) Ethyleneimine* (1 w/w%) Ethylene oxide* (1 w/w%) Vinyl chloride* (1 w/w%) Chloromethyl methyl ether* (1 w/w%) 3,3'-Dichloro-4,4'-diaminodiphenylmethane* (1 w/w%) Nickel carbonyl* (1 w/w%) p-Dimethylaminoazobenzene* (1 w/w%) β-Propiolacton* (1 w/w%) Benzene* (1 w/w%) Auramine* (1 w/w%) Magenta* (1 w/w%) Chromic acid and its salts* (1 w/w%) Dichromic acid and its salts* (1 w/w%) Asbestos (excluding Amosite and Crocidolite)* (1 w/w%) Arsenic trioxide* (1 w/w%) Coal tar* (5 w/w%) Alkylmercury compounds (restricted to the substances in which the alkyl radicals are methyl or ethyl radicals) (1 w/w%) o-Phthalodinitrile (1 w/w%) Cadmium and its compounds (1 w/w%) Vanadium pentoxide (1 w/w%) Potassium cyanide (5 w/w%) Sodium cyanide (5 w/w%) Mercury and its inorganic compounds (1 w/w%) Nitroglycol (1 w/w%) Pentachlorophenol (1 w/w%) Manganese and its compounds (excluding basic manganese oxides) (1 w/w%) Type 3 Substances (9 substances)
Sulfuric acid (1 w/w%)
Nitric acid (1 w/w%)
Hydrogen chloride (1 w/w%)
Sulfur dioxide (1 w/w%)
Carbon monoxide (1 w/w%)
Ammonia (1 w/w%)
Phosgene (1 w/w%)
Phenol (5 w/w%)
Formaldehyde (1 w/w%)
Table 3. Poisonous Substances
(Designated by Poisonous and Deleterious Substances Control Law) Note: Substances with asterisk are the specified poisonous substances. O-Ethyl O-(p-nitrophenyl) phenylphosphonothioate (otherwise known as EPN) 3 1,3,4,5,6,7.8.8-Octachloro-1,3,3a,4,7.7a-hexahydro-4,7-methanoisobenzofuran 4 Octamethylpyrophosphoramide (otherwise known as Schradan)* O,O-Diethyl O-(p-nitrophenyl) thiophosphate (otherwise known as Parathion)* 10 Dinitrocresol 11 2,4-Dinitro-6-(1-methylpropyl)-4,6-dinitrophenol 12 S-(2-Ethylthioethyl) O,O-dimethyl thiophosphate (otherwise known as Methyldimeton)* 13 2-Chloro-2-diethylcarbamoyl-1-methylethenyl dimethyl phosphate * 14 O,O-Dimethyl O-(p-nitrophenyl) thiophosphate (otherwise as methylparathion)* 15 Mercury 16 Selenium 17 Thiosemicarbazide 18 Tetraethyl pyrophosphate (otherwise known as TEPP)* 23 1,2,3,4,10,10-Hexachloro-6,7-epoxy-1,4,4a,5,6,7,8,8a-octahydro-endo,endo- 1,4:5,8-dimethanonaphthalene (otherwise known as Endrin) 24 6,7,8,9,10,10-Hexachloro-1,5,5a,6,9,9a-hexahydro-6,9-methano-2,4,3- In addition to the above substances, any preparation containing any one of the above substances, or any highly toxic substance designated by a separate ordinance List of Specified Poisonous Substances
Anyone using, receiving (buying), or possessing the specified poisonous substances without a researcher license for the specified poisonous substances will be charged under the Poisonous and Poisonous and Deleterious Substances Control Law (Clause 3, Article 2)
Under this law, the specified poisonous substances are poisonous substances shown in Attached Table 3. Attached Table 3: Specified poisonous substances O,O-Diethyl O-(p-nitrophenyl) thiophosphate S-(2-Ethylthioethyl) O,O-dimethyl thiophosphate 2-Chloro-2-diethylcarbamoyl-1-methylethenyl dimethyl phosphate O,O-Dimethyl O-(p-nitrophenyl) thiophosphate In addition to the above poisonous substances, any preparation containing any one of the above substances, or any highly toxic substance designated by a separate ordinance Poisonous and Deleterious Substances Designated Law (Article 3)
Based on Attached Table 3, No. 10, the following poisonous substances are designated as specified Any preparation containing octamethylpyrophosphoramide 2 Any preparation containing tetraalkyllead 3 Any preparation containing O,O-diethyl O-(p-nitrophenyl) thiophosphate Any preparation containing S-(2-ethylthioethyl) O,O-dimethyl thiophosphate Any preparation containing 2-chloro-2-diethylcarbamoyl-1-methylethenyl dimethyl Any preparation containing O,O-dimethyl O-(p-nitrophenyl) thiophosphate Any preparation containing tetraethyl pyrophosphate Salts of monofluoroacetic acid and any preparation containing them Any preparation containing monofluoroacetamide Any preparation containing aluminium phosphide and its decomposition-promotion reagent Table 4. Deleterious Substances
(Designated by Poisonous and Deleterious Substances Control Law) 1 Acrylonitrile 2 Acrolein 3 Aniline 4 Ammonia 5 O,O-Diethyl O-(2-isopropyl-4-methyl-6-pyrimidyl) thiophosphate (otherwise known as Diazinon) N-(diethyldithiophosphorylacetyl)-N-methylcarbamate S-(4-Chlorophenylthiomethyl) O,O-diethyl dithiophosphate O-(2,4-Dichlorophenyl) O,O-diethyl thiophosphate S-(2,5-Dichlorophenylthiomethyl) O,O-diethyl dithiophosphate 29 1,4-Dichlorobutyne 30 2,3-Bis(diethyldithiophosphoro)-1,4-dioxane 31 2-Cyclohexyl-4,6-dinitrophenol 32 2-(1-Methylpropyl)-4,6-dinitrophenyl acetate 33 2-(1-Methylpropyl)-4,6-dinitrophenyl 3,3-dimethylacrylate 34 1,1’-Ethylene-2,2’-bipyridylium dibromide 35 1,2-Dibromoethane (otherwise known as EDB) 37 3,5-Dibromo-4-hydroxy-4'-nitroazobenzene 38 S-(2-Ethylsulfinyl-1-methylethyl) O,O-dimethyl dithiophosphate S-(2-Ethylthioethyl) O,O-dimethyl dithiophosphate (otherwise known as Thiometon) 2,2-Dichloroethenyl dimethyl phosphate (otherwise known as DDVP) 42 1,2-Dibromo-2,2-dichloroethyl dimethyl phosphate 43 O,O-Dimethyl S-phthalimidomethyl dithiophosphate O,O-Dimethyl S-(N-methylcarbamoylethylthioethyl) thiophosphate O,O-Dimethyl S-(N-methylcarbamoylmethyl) dithiophosphate (otherwise known as O,O-Dimethyl O-(3-methyl-4-methylthiophenyl) thiophosphate O,O,O’,O’-Tetraethyl S,S’-methylene phosphorodithioate 2,2,2-trichloro-1-hydroxyethylphosphonate 60 1,2,5-Trithiocycloheptadiene-3,4,6,7-tetranitrile 61 Toluidine 62 Sodium 63 Nitrobenzene 64 Carbon Picric acid (however, exclusive of explosives) 69 Hydroxylamine 70 Phenol 71 Blasticiden 74 Bromomethane 75 1,2,3,4,10,10-Hexachloro-6,7-epoxy-1,4,4a,5,6,7,8,8a-octahydro-1,4-endo,exo- 5,8-dimethanonaphthalene (otherwise known as Dieldrin) 1,2,3,4,5,6-Hexachlorocyclohexane (otherwise known as Lindane) 77 1,2,3,4,10,10-Hexachloro-1,4,4a,5,8,8a-hexahydro-1,4-endo,exo-5,8- dimethanonaphthalene (otherwise known as Aldrin) 79 1,4,5,6,7,8,8-Heptachloro-3a,4,7,7a-tetrahydo-4,7-methano-1H-indene Pentachlorophenol (otherwise known as PCP) 83 Methanol 84 Methylsulfonal 85 1-Naphtyl In addition to the above substances, any preparation containing any one of the above substances, or any toxic substance designated by a separate ordinance Table 5. Narcotics (Narcotics and Psychoactive Drugs Control Law)
1. Narcotics and Home Narcotics (No. 76, a)
3-Acetoxy-6-dimethylamino-4,4-diphenylheptane (otherwise known as Acetylmethadol) and its salts -3-Acetoxy-6-dimethylamino-4,4-diphenylheptane (otherwise known as -Acetylmethadol) and its salts -3-Acetoxy-6-dimethylamino-4,4-diphenylheptane (otherwise known as -Acetylmethadol) and its salts -3-Acetoxy-6-dimethylamino-4,4-diphenylheptane (otherwise known as -Acetylmethadol) and its salts 5 1-[2-(4-Aminophenyl)ethyl]-4-phenylpiperidine-4-carboxylic acid ethyl ester (otherwise N-Allylnormorphine (otherwise known as Nalorphine) and its salts 3-Allyl-1-methyl-4-phenyl-4-(propionyloxy)piperidine (otherwise known as Allylprodine) 3-(N-Ethyl-N-methylamino)-1,1-di(2-thienyl)-1-butene (otherwise known as Ethylmethyl- thiambutene) and its salts 10 -3-Ethyl-1-methyl-4-phenyl-4-(propionyloxy)piperidine (otherwise known as -3-Ethyl-1-methyl-4-phenyl-4-(propionyloxy)piperidine (otherwise known as 2-(4-Chlorobenzyl)-1-(diethylamino)ethyl-5-nitrobenzimidazole (otherwise known as Cocaine, Ecgonin and other esters and these salts Codeine and ethylmorphine and other morphine ether and these salts Diacetylmorphine (otherwise known as Heroin) and other morphine esters and these salts 17 1-(3-Cyano-3,3-diphenylpropyl)-4-phenylpiperidine-4-carboxylic acid ethyl ester (otherwise known as Diphenoxylate) and its salts 18 4-Cyano-2-dimethylamino-4,4-diphenylbutane (otherwise known as Methadone Intermediate) and its salts 4-Cyano-1-methyl-4-phenylpiperidine (otherwise known as Pethidine Intermediate A) and its salts 20 1-(Diethylamino)ethyl-2-(4-ethoxybenzyl-5-nitrobenzimidazole (otherwise known as Etonitazene) and its salts 21 3-Diethylamino-1,1-di(2-thienyl)-1-butene (otherwise known as Diethylthiambutene) and its salts Dihydrocodeinone (otherwise known as Hydrocodone) and its salts Dihydrocodeine and its esters and these salts Dihydrodeoxymorphine (otherwise known as Desomorphine) and its salts Dihydrohydroxycodeinone (otherwise known as Oxycodone) and its esters and these salts Dihydrohydroxymorphinone (otherwise known as Oxymorphone) and its salts Dihydromorphine and its esters and these salts Dihydromorphinone (otherwise known as Hydromorphone) and its esters and these salts 4,4-Diphenyl-6-piperidino-3-heptanone (otherwise known as Dipipanone) and its salts 30 (2-Dimethylamino)ethyl-1-ethoxy-1,1-diphenylacetate (otherwise known as Dimenoxadol) 31 3-Dimethylamino-1,1-di(2-thienyl)-1-butene (otherwise known as Desomorphine) and its 6-Dimethylamino-4,4-diphenyl-3-hexanone (otherwise known as Normethadone) and its 33 6-Dimethylamino-4,4-diphenyl-3-heptanol (otherwise known as Dimepheptanol) and its -6-Dimethylamino-4,4-diphenyl-3-heptanol (otherwise known as -Methadol) and its -6-Dimethylamino-4,4-diphenyl-3-heptanol (otherwise known as -Methadol) and its salts 36 6-Dimethylamino-4,4-diphenyl-3-heptanone (otherwise known as Methadone) and its salts 4-Dimethylamino-3-methyl-1,2-diphenyl-2-(propionyloxy)butane (otherwise known as 6-Dimethylamino-5-methyl-4,4-diphenyl-3-hexanone (otherwise known as Isomethadone) and its salts 39 1,3-Dimethyl-4-phenyl-4-(propionyloxy)azacycloheptane (otherwise known as -1,3-Dimethyl-4-phenyl-4-(propionyloxy)piperidine (otherwise known as -Prodine) -1,3-Dimethyl-4-phenyl-4-(propionyloxy)piperidine (otherwise known as -Prodine) 1,2,5-Trimethyl-4-phenyl-4-(propionyloxy)piperidine (otherwise known as Trimeperidine) and its salts 6-Nicotinylcodeine (otherwise known as Nicocodine) and its salts Normorphine (otherwise known as Demethylmorphine) and its esters and these salts 1-[2-(2-Hydroxyethoxy)ethyl]-4-phenylpiperidine-4-carboxylic acid ethyl ester (otherwise known as Ethoxeridine) and its salts 47 14-Hydroxydihydromorphine (otherwise known as Hydromorphinol) and its salts 3-Hydroxy-N-phenacylmorphinan (excluding of dextrorotatory) and its salts 1-(3-Hydroxy-3-phenylpropyl)-4-phenylpiperidine-4-carboxylic acid ethyl ester (otherwise known as Phenoperidine) and its salts 50 4-(3-hydroxyphenyl)-1-methyl-4-piperidylethylketone (otherwise known as Ketobemidone) and its salts 4-(3-Hydroxyphenyl)-1-methylpiperidine-4-carboxylic acid ethyl ester (otherwise known as Hydroxypethidine) and its salts 3-Hydroxy-N-phenethylmorphinan (otherwise known as Phenomorphan) and its salts 3-Hydroxy-N-methylmorphinan (excluding of dextrorotatory) and its salts 3-Hydroxymorphinan (excluding of dextrorotatory) and its salts 4-Phenyl-1-[2-(tetrahydrofurfuryloxy)ethyl]piperidine-4-carboxylic acid ethyl ester (otherwise known as Furethidine) and its salts 56 4-Phenylpiperidine-4-carboxylic acid ethyl ester (otherwise known as Pethidine Intermediate B) and its salts 4-Phenyl-1-(3-phenylaminopropyl)piperidine-4-carboxylic acid ethyl ester (otherwise known as Piminodine) and its salts 58 1,2,3,4,5,6-Hexahydro-8-hydroxy-6,11-dimethyl-3-phenethyl-2,6-methano-3-benzazocine (otherwise as Phenazocine) and its salts 59 1,2,3,4,5,6-Hexahydro-8-hydroxy-3,6,11-trimethyl-2,6-methano-3-benzazocine (otherwise known as Metazocine) and its salts 60 1-[2-(Benzyloxy)ethyl]-4-phenylpiperidine-4-carboxylic acid ethyl ester (otherwise known as Benzethidine) and its salts 6-Methyldihydromorphine (otherwise known as Methyldihydromorphine) and its salts Methyldihydromorphinone (otherwise known as Metopon) and its esters and these salts 6-Methyl- -6-deoxymorphine (otherwise known as Methyldesorphine) and its salts 64 N-(1-Methyl-2-piperidinoethyl)propionanilide (otherwise known as Phenampromide) and 1-Methyl-4-phenylpiperidine-4-carboxylic acid esters and these salts N-[2-(Methylphenethylamino)propyl]propionanilide (otherwise known as Diampromide) and its salts [(3-Methyl-4-morpholino-2,2-diphenyl)butyryl]pyrrolidine and its salts 3-Methyl-4-morpholino-2,2-diphenylbutanoic acid (otherwise known as Moramide Intermediate) and its salts 3-Methoxy-N-methylmorphinan (excluding of dextrorotatory) and its salts Morphine-N-oxide and other pentavalent nitrogen morphines and these derivatives 1-(2-Morpholinoethyl)-4-phenylpiperidine-4-carboxylic acid ethyl ester (otherwise known as Morpheridine) and its salts 6-Morpholino-4,4-diphenyl-3-heptanone (otherwise known as Phenadoxone) and its salts 4-Morpholino-2,2-diphenylbutyric acid ethyl ester (otherwise known as Dioxaphetyl butyrate) and its salts Substances with an veruse risk and a toxic effect similar to the substances shown in above numbers, designated by a government ordinance 76 Substances containing any one of the substances shown in the above numbers except for opium. The following substances are excluded.
a) Substances containing less than 10/1000 of codeine, dihydorocodeine or these salts, but
not containing the substances other than these shown in above each number
b) Plants (including their parts) other than those for the ingredients of narcotics
2. Opium
3. Poppy straw
4. Plants for ingredients of narcotics

1
Erythroxylum novogranatense (Morris) Hieron. Papaver bracteatum Lindl. (Japanese Hakamaonigeshi) 4 Other plants designated by a government ordinance Table 6. Psychoactive drugs (Narcotics and Psychoactive Drugs Control Law)
5-Ethyl-5-phenylbarbituric acid (otherwise known as Phenobarbital) and its salts 5-Ethyl-5-(1-methylbutyl)barbituric acid (otherwise known as Pentbarbital) and its 3 7-Chloro-1,3-dihydro-1-methyl-5-phenyl-2H-1,4-benzodiazepin-2-one (otherwise known as Diazepam) and its salts 4 10-Chloro-2,3,7,11b-tetrahydro-2-methyl-11b-phenyloxazoro[3,2-d][1.4]- benzodiazepin-6(5H)-one (otherwise known as Oxazolam) and its salts 5 5-(2-Chlorophenyl)-7-ethyl-1,3-dihydro-1-methyl-2H-thieno[2,3-e]-1,4-diazepin- 2-one (otherwise known as Clotiazepam) and its salts 6 7-Chloro-2-methylamino-5-phenyl-3H-1,4-benzoazepin-4-oxide known as Chlordiazepoxide) and its salts 7 5,5-Diethyl-barbituric acid (otherwise known as Barbital) and its salts 8 1,3-Dihydro-7-nitro-5-phenyl-2H-1,4-benzodiazepin-2-one (otherwise known as Nitrazepam) and its salts 9 2-Phenyl-2-(2-piperidyl)acetic acid methyl ester (otherwise known as Methylphenidate) and its salts 10 1,2,3,4,5,6-Hexahydro-6,11-dimethyl-3-(3-methyl-2-butenyl)-2,6-methano-3- benzazocin-8-ol (otherwise known as Pentazocine) and its salts 11 Substances with an overuse risk and a toxic effect similar to the substances shown in above each number, designated by a government ordinance 12 Any preparation containing any one of the above substances Table 7. Stimulants and Ingredients of Stimulants (Stimulants Control Law)
Stimulants
Phenylaminopropane, phenylmethylaminopropane and their salts Substance containing any one of the above substances Ingredients of Stimulants
1-Phenyl-2-methylaminopropanol-1 (Ephedrine), its salts, and substances containing any 1-Phenyl-1-chloro-2-methylaminopropane (Chloroephedrine), its salts, and substances containing any one of these substances 3 1-Phenyl-2-dimethylaminopropanol-1 (Methylephedrine), its salts, and substances containing any one of these substances 4 1-Phenyl-1-chloro-2-methylaminopropane (Chloroephedrine), its salts, and substances containing any one of these substances 5 1-Phenyl-1-chloro-2-dimethylaminopropane (Chloromethylephedrine), its salts, and substances containing any one of these substances 6 Phenylacetic acid, its salts, and substances containing any one of these substances Phenylacetonitrile and substances containing this Phenylacetone and substances containing this 9 N, -Dimethyl-N-2-propynylphenethylamine (Selegiline), its salts, and substances containing any one of these substances 10 Erythro-2-amino-1-phenylpropane-1-ol (Norephedrne), its salts, and substances containing any one of these substances Substances containing less than 10% of three substances (Nos. 1, 3, and 6) and substances containing less than 50% of a substance (No 10) are ruled out from the ingredients of stimulants. Table 8. Hazardous Substances
10 Any substance designated by a separate ordinance (Periodates, Periodic acid, Oxides of chromium, lead and iodine, Nitrites, Hypochlorites, Chlorinated isocyanuric acid, Peroxodisulfates, and Peroxoborates) 11 Substances including any of above items 7 Any substance designated by a separate ordinance 8 Substances including any of above items Substances ignitable spontaneously, or 1 Potassium reactive with water. 6 Alkaline metals (excluding potassium and sodium), and alkaline earth metals 7 Organometallic compounds (excluding alkylaluminum and alkyllithium) 9 Metal phosphides 10 Calcium carbide or Aluminum carbide 11 Any substance designated by a separate ordinance (Chlorinated silicon compounds) 12 Substances including any of above items 8 Any substance designated by a separate ordinance (Metal azides, Guanidinium nitrate) 9 Substances including any of above items 4 Any substance designated by a separate ordinance (Halogen-halogen compounds) 5 Substances including any of above items Table 9. Gases with Special Components
Note: Substances indicated by an asterisk are special high-pressure gases. Monosilane (SiH4)*, Trichlorosilane (SiHCl3), Silicon tetrafluoride (SiF4), Dichlorosilane (SiH2Cl2), Silicon tetrachloride (SiCl4), Disilane (Si2H6)* Arsine (AsH3)*, Arsenic(V) fluoride (AsF5), Arsenic(V) chloride (AsCl5), Arsenic(III) fluoride (AsF3), Arsenic(III) chloride (AsCl3) Phosphine (PH3)*, Phosphorus(V) fluoride (PF5), Phosphorus(V) chloride (PCl5), Phosphorus(III) fluoride (PF3), Phosphorus(III) chloride (PCl3), Phosphorus oxychloride (POCl3) Diborane (B2H6)*, Boron trichloride (BCl3), Boron trifluoride (BF3), Boron tribromide (BBr3) Trialkylgallium (GaR3), Trialkylindium (InR3) Hydrogen selenide (H2Se)*, Hydrogen telluride (H2Te), Tin hydride (SnH4), Monogermane (GeH4)*, Stibine (SbH3) Nitrogen trifluoride (NF3), Tungsten(VI) fluoride (WF6), Germanium tetrachloride (GeCl4), Antimony(V) chloride (SbCl5), Molybdenum(V) chloride (MoCl5), Fluorine (F2), Sulfur tetrafluoride (SF4), Molybdenum(VI) fluoride (MoF6), Tin(IV) chloride (SnCl4), Tungsten(VI) chloride (WCl6), Hydrogen fluoride (HF)

Source: https://www.s.u-tokyo.ac.jp/en/offices/esmo/pdf/manual_table_1-9.pdf