PRODUCT NAME RAID COMMERCIAL INSECTICIDE ODOURLESS FLY AND INSECT KILLER 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Supplier Name JOHNSONDIVERSEY AUSTRALIA PTY LTD
29 Chifley St, Smithfield, NSW, AUSTRALIA, 2164
Telephone Emergency Email Web Site Synonym(s)
739400 RAID ODOURLESS FLY AND INSECT KILLER 12 X 400G
AEROSOL DISPENSED, FLY SPRAY, INSECTICIDE
2. HAZARDS IDENTIFICATION NOT CLASSIFIED AS HAZARDOUS ACCORDING TO NOHSC CRITERIA CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE Hazchem Code Pkg Group Subsidiary Risk(s) 3. COMPOSITION / INFORMATION ON INGREDIENTS Ingredient 4. FIRST AID MEASURES
Hold eyelids apart and flush continuously with water. Continue until advised to stop by the Poisons InformationCentre, a doctor, or for at least 15 minutes. Keep patient calm. Inhalation
If over exposure occurs leave exposure area immediately. If irritation persists, seek medical attention.
Gently flush affected areas with water. Seek medical attention if irritation develops. Ingestion
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor. If swallowed, do notinduce vomiting. Ingestion is considered unlikely due to product form. Advice to Doctor First Aid
Eye wash facilities should be provided. Facilities PRODUCT NAME RAID COMMERCIAL INSECTICIDE ODOURLESS FLY AND INSECT KILLER 5. FIRE FIGHTING MEASURES Flammability
Highly flammable. Vapours may form explosive mixtures with air. May evolve toxic gases (carbon oxides,hydrocarbons) when heated to decomposition.Eliminate all ignition sources including cigarettes, open flames,spark producing switches/tools, heaters, naked lights, pilot lights, mobile phones etc. when handling. Aerosol cansmay explode when heated above 50 C.
Highly flammable - explosive vapour. Evacuate area and contact emergency services. Toxic gases may be
evolved when heated. Remain upwind and notify those downwind of hazard. Wear full protective equipment (seespill above) including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to coolintact containers and nearby storage areas. Extinguishing
Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains or waterways, absorb runoff withsand or similar. Hazchem Code 6. ACCIDENTAL RELEASE MEASURES Spillage
If aerosol can damaged/leaking, ventilate and clear area of all unprotected personnel. Wear splash-proof goggles,PVC/rubber gloves, a Type A-Class P1 (Organic vapour and Particulate) respirator (where an inhalation riskexists) and coveralls. Collect and allow to discharge outdoors. Absorb residues with sand or similar and place inclean containers for disposal. 7. STORAGE AND HANDLING
Store in cool, dry, well ventilated area, removed from oxidising agents, acids, alkalis, direct sunlight, heat orignition sources, foodstuffs, out of direct sunlight and out of the reach of children. Ensure containers areadequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks orspills. Large storage areas should have appropriate fire protection. Handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skincontact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating,drinking and smoking in contaminated areas (eg. if container is damaged). 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Ventilation
Do not inhale vapours. Use in well ventilated areas. In poorly ventilated areas, mechanical extraction ventilation isrecommended.Flammable/explosive vapours may accumulate in poorly ventilated areas. Vapours are heavierthan air and may travel some distance to an ignition source and flash back.Maintain vapour levels below therecommended exposure standard. Exposure
LIQUEFIED PETROLEUM GAS (LPG) (68476-85-7)
ES-TWA: 1000 ppm (1800 mg/m3) WES-TWA: 1000 ppm (1800 mg/m3)HYDROTREATED HEAVY NAPHTHA (PETROLEUM) (64742-48-9) ES-STEL : 400 ppm (1800 mg/m3)TETRAMETHRIN (7696-12-0) ES-STEL : 10 mg/m3 - Pyrethrins (ACGIH) ES-TWA: 5 mg/m3 - Pyrethrins (ACGIH)
With prolonged use, wear safety glasses, splash-proof goggles and rubber or PVC gloves. Where an inhalationrisk exists, wear a Type A-Class P1 (Organic vapour and Particulate) Respirator. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Solubility (water): Specific Gravity: % Volatiles: Vapour Pressure: Flammability: Vapour Density: Flash Point: Boiling Point: Upper Explosion Limit: Melting Point: Lower Explosion Limit: Evaporation Rate: Autoignition Temperature: Exposure Standard: PRODUCT NAME RAID COMMERCIAL INSECTICIDE ODOURLESS FLY AND INSECT KILLER 10. STABILITY AND REACTIVITY Reactivity
Incompatible with oxidising agents (eg. hypochlorites, peroxides), acids (eg. sulphuric acid), strong alkalis (eg. hydroxides), heat and ignition sources. Decomposition
May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Products 11. TOXICOLOGICAL INFORMATION Health Hazard
This product has the potential to cause adverse health effects with chronic or high level exposure. Use safe work
practices (ie. do not overspray or contaminate non target areas) to avoid eye-skin contact and vapour inhalation.
Contact may result in lacrimation, irritation, pain, redness and conjunctivitis. Prolonged contact - corneal burnsand possible permanent damage. Inhalation
Over exposure may result in mucous membrane irritation of the respiratory tract and sneezing. At high levels,pyrethrins may cause breathing difficulties (wheezing) and sensitisation with asthma like symptoms.
Prolonged contact may result in irritation, redness, rash, dermatitis and sensitisation. Toxic effects may result fromskin absorption. Ingestion
Due to product form (aerosol container) ingestion is considered highly unlikely. Toxicity Data
PERMETHRIN (52645-53-1) LC50 (Inhalation): 485 mg/m3 (rat) LD50 (Ingestion): 383 mg/kg (rat) LD50 (Skin): 1750 mg/kg (rat)SODIUM NITRITE (7632-00-0) LC50 (Inhalation): 5.5 mg/m3/4 hours (rat) LD50 (Ingestion): 180 mg/kg (rat)TETRAMETHRIN (7696-12-0) LC50 (Inhalation): 2 g/m3 (mouse) LD50 (Ingestion): 1000 mg/kg (mouse) LD50 (Skin): 2500 ug/kg (rat)
12. ECOLOGICAL INFORMATION Environment
Limited ecotoxicity data was available for this product at the time this report was prepared. Ensure appropriatemeasures are taken to prevent this product from entering the environment. 13. DISPOSAL CONSIDERATIONS Waste Disposal
For small amounts absorb contents with sand or similar and dispose of to an approved landfill site. Do not punctureor incinerate aerosol cans. Contact the manufacturer for additional information. Legislation
Dispose of in accordance with relevant local legislation. 14. TRANSPORT INFORMATION Shipping Name Hazchem Code Pkg Group Subsidiary Risk(s) 15. REGULATORY INFORMATION Poison
A poison schedule number has not been allocated to this product using the criteria in the Standard for the
Uniform Scheduling of Drugs and Poisons (SUSDP).
All chemicals listed on the Australian Inventory of Chemical Substances (AICS). 16. OTHER INFORMATION Additional Information
SYNERGISM - ANTAGONISM: Ingredients in this product may act together to aggravate or reduce adverseeffects. Accordingly the time weighted average concentration (TWA) provided for single ingredients should beconsidered as a guide only and all due care exercised when handling.
AEROSOL CANS may explode at temperatures approaching 50 C.
ABBREVIATIONS:mg/m3 - Milligrams per cubic metreppm - Parts Per Million
PRODUCT NAME RAID COMMERCIAL INSECTICIDE ODOURLESS FLY AND INSECT KILLER
TWA/ES - Time Weighted Average or Exposure Standard. CNS - Central Nervous SystemNOS - Not Otherwise SpecifiedpH - relates to hydrogen ion concentration - this value will relate to a scale of 0 - 14, where 0 is highly acidic and14 is highly alkaline. CAS# - Chemical Abstract Service number - used to uniquely identify chemical compounds. M - moles per litre, a unit of concentration. IARC - International Agency for Research on Cancer.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this Chem Alert report is provided as a guideonly. Factors such as method of application, working environment, quantity used, product concentration and theavailability of engineering controls should be considered before final selection of personal protective equipment ismade.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factors including:frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used andmethod of application. Given that it is impractical to prepare a Chem Alert report which would encompass allpossible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate. Report Status
This document has been compiled by RMT on behalf of the manufacturer of the product and serves as themanufacturer's Material Safety Data Sheet ('MSDS').
It is based on information concerning the product which has been provided to RMT by the manufacturer orobtained from third party sources and is believed to represent the current state of knowledge as to theappropriate safety and handling precautions for the product at the time of issue. Further clarification regardingany aspect of the product should be obtained directly from the manufacturer.
While RMT has taken all due care to include accurate and up-to-date information in this MSDS, it does notprovide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for anyloss, injury or damage (including consequential loss) which may be suffered or incurred by any person as aconsequence of their reliance on the information contained in this MSDS. Prepared By
Risk Management Technologies5 Ventnor Ave, West PerthWestern Australia 6005Phone: +61 8 9322 1711Fax: +61 8 9322 1794Email: [email protected]: www.rmt.com.au
MSDS Date: 25 October 2006 End of Report
Date: 11/02/2011 Dear Pharmacist RE: BENDROFLUMETHIAZIDE 2.5MG TABLETS BENDROFLUMETHIAZIDE 5MG TABLETS I am writing to inform you that Dr Reddy’s Laboratories (UK) Ltd is issuing a warning in use notice for Bendroflumethiazide 2.5mg Tablets and Bendroflumethiazide 5mg Tablets. This warning affects the following batches: Following an internal audit, it was found that an out of date