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Material Safety Data Sheet
MSDS Number: 1704
PERMANONE 30-30 MSDS Version 1.0
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SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Product Name PERMANONE 30-30
Chemical Name
Synonym
MSDS Number 1704
Chemical Family Mixture
Chemical Formulation Mixture
EPA Registration No. 432-1235
Canadian Registrat. No.
Aventis
95 Chestnut Ridge Road
Montvale, NJ 07645
USA
For Product Use Information: (800)331-2867 Monday through Friday
8:00AM-4:30PM
For Medical Emergency contact DART: (800) 334-7577 24 Hours/Day
For Transportation Emergency CHEMTREC: (800) 424-9300 24 Hours/Day
Product Use Description Permanone 30-30 ULV is recommended for application as an Ultra
Low Volume
(U.L.V.) nonthermal aerosol (Cold Fog) to control adult mosquitoes, biting and
non-biting midges and blackflies in residential and recreational areas.
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
Component Name CAS No. Concentration % by Weight
Minimum Maximum
Permethrin 52645-53-1 30.0000
Piperonyl butoxide 51-03-6 30.0000
Inert ingredients 40.0000
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SECTION 3. HAZARDS IDENTIFICATION
NOTE: Please refer to Section 11 for detailed toxicological information.
Emergency Overview CAUTION. KEEP OUT OF REACH OF CHILDREN
Health: Harmful if swallowed, absorbed through skin or inhaled. Prolonged or
frequently repeated skin contact may cause allergic reactions in some
individuals. Avoid contact with skin, eyes or clothing. Avoid breathing vapors.
Wash thoroughly with soap and water after handling.
Environmental: This product is extremely toxic to fish and aquatic invertebrates
and highly toxic to bees.
Physical State liquid
Odor Mild sassafrass-type
Appearance Thick, dark amber
Routes of Exposure Ingestion, inhalation, and skin contact.
Immediate Effects
Eye Causes moderate eye damage injury.
Skin Harmful if absorbed. Prolonged or frequently repeated skin contact may cause
allergic reactions in some individuals. Slightly irritating.
Ingestion Harmful if swallowed.
Inhalation Harmful if inhaled.
Chronic or Delayed
Long-Term
See Section 11 for carcinogenic/oncogenic information on piperonyl butoxide
and permethrin.
Medical Conditions
Aggravated by Exposure
None known.
SECTION 4. FIRST AID MEASURES
Eye Hold eye open and rinse slowly and gently with water for 15-20 minutes.
Remove contact lenses, if present, after the first 5 minutes, then continue rinsing
eye. Call a poison control center or doctor for treatment advice.
Skin Take off contaminated clothing. Rinse skin immediately with plenty of water for
15-20 minutes. Call a poison control center or doctor for treatment advice.
Ingestion Call a Poison Control Center or doctor immediately for treatment advice. Do not
induce vomiting unless told to do so by the poison control center or doctor. Do
not give anything by mouth to an unconscious person.
Inhalation Move person to fresh air. If person is not breathing, call 911 or an ambulance,
then give artificial respiration, perferably mouth-to-mouth if possible. Call a
poison control center or doctor for further treatment advice.
Note to Physician Have the product container or label with you when calling a poison control
center
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or doctor or going for treatment.
This product contains a pyrethroid. If a small amount is ingested (or if treatment
is delayed) oral administration of large amounts of activated charcoal and a
cathartic is probably sufficient therapy.
Do not administer milk, cream or other substances containing vegetable or
animal fats, which enhance the absorption of lipophilic substances.
SECTION 5. FIRE FIGHTING MEASURES
Flash Point 129 °C / 264 °F
TCC
Suitable Extinguishing
Media
Carbon dioxide, dry chemical, foam or water.
Fire Fighting
Instructions
As in any fire, wear self-contained breathing apparatus pressure-demand,
MSHA/NIOSH approved (or equivalent) and full protective gear.
SECTION 6. ACCIDENTAL RELEASE MEASURES
General and Disposal Soak up with an absorbent material such as sawdust or fuller's earth,
sweep up
and place in a labeled container.
SECTION 7. HANDLING AND STORAGE
Handling Procedures Avoid contact with skin, eyes or clothing. Avoid breathing vapors or spray
mist.
Storing Procedures Do not contaminate water, food or feed by storage or disposal.
Do not use, pour, spill or store near heat or open flame.
Do not store at temperatures below 40°F (4.5°C). If this material has been
exposed to temperatures below 40°F (4.5°C) there may be precipitation. Check
for crystalization. If evident, warm to 80°F (26.5°C) and thoroughly mix before
using. DO NOT USE OPEN FLAME.
Store product inits original container in a cool, dry, locked place designated for
such insecticides and out of reach of children. Avoid exposure to extreme
temperatures.
Work/Hygienic
Procedures
Wash thoroughly with soap and water after using and before eating or smoking.
Remove contaminated clothing and wash before reuse.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye/Face Protection Safety glasses or goggles.
Body Protection Impervious gloves.
Exposure Limits None Established
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Thick, dark amber
Physical State liquid
Odor Mild sassafrass-type
Bulk Density 8.1837 lbs/gal
Solubility (in water) insoluble
SECTION 10. STABILITY AND REACTIVITY
Chemical Stability Stable
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Incompatibility Strong oxidizing agents.
Hazardous
Polymerization
(Conditions to avoid)
Will not occur
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity LD50 rat 1,250 mg/kg
This data was obtained using Permanone 31% Butacide 66% Manufacturing
Concentrate; EPA Reg. No. 432-1150, which contains 31% permethrin and 66%
piperonyl butoxide.
LD50 rat (female) 396 mg/kg
This data was obtained using Permethrin, the active ingredient.
Acute Dermal Toxicity LD50 rat 2,020 mg/kg
This data was obtained using Permanone 31% Butacide 66% Manufacturing
Concentrate; EPA Reg. No. 432-1150, which contains 31% permethrin and 66%
piperonyl butoxide.
LD50 rat (male) > 5,176 mg/kg
This data was obtained using Permethrin, the active ingredient.
LD50 rat (female) > 4,000 mg/kg
This data was obtained using Permethrin, the active ingredient.
Acute Inhalation Toxicity LC50 rat 4.39 mg/l
(4.0 h)
This data was obtained using Permanone 31% Butacide 66% Manufacturing
Concentrate; EPA Reg. No. 432-1150, which contains 31% permethrin and 66%
piperonyl butoxide.
LC50 rat 17.56 mg/l for DOT purposes
(1.0 hr)
This data was obtained using Permanone 31% Butacide 66% Manufacturing
Concentrate; EPA Reg. No. 432-1150, which contains 31% permethrin and 66%
piperonyl butoxide.
Skin Irritation rabbit Slightly irritating
This data was obtained using Permanone 31% Butacide 66% Manufacturing
Concentrate; EPA Reg. No. 432-1150, which contains 31% permethrin and 66%
piperonyl butoxide.
Eye Irritation rabbit Tox Category III Mildly irritating
This data was obtained using Permanone 31% Butacide 66% Manufacturing
Concentrate; EPA Reg. No. 432-1150, which contains 31% permethrin and 66%
piperonyl butoxide.
Sensitization guinea pig Sensitizing
This data was obtained using Permanone 31% Butacide 66% Manufacturing
Concentrate; EPA Reg. No. 432-1150, which contains 31% permethrin and 66%
piperonyl butoxide.
Chronic Toxicity A statistically significant increase in the incidence of lung and liver tumors was
observed in female mice receiving diets containing 375 and 750 mg/kg/day of
permethrin technical over 85 weeks.
A statistically significant increase in the number of benign liver tumors appeared
in mice fed piperonyl butoxide technical at doses which far exceed any
anticipated daily human intake. Independent and industry toxicological experts
who have reviewed the data agree that the findings of the study do not indicate a
health risk to human beings.
Assessment Carcinogenicity
ACGIH
None
NTP
None
IARC
Permethrin 52645-53-1
Piperonyl butoxide 51-03-6
OSHA
None
SECTION 12. ECOLOGICAL INFORMATION
Environmental
Precautions
This product is extremely toxic to fish and aquatic organisms. For terrestrial
uses, do not apply directly to water, or to areas where surface water is present,
or to intertidal areas below mean high water mark. Do not apply when weather
conditions favor drift from areas treated. Drift or runoff from treated areas may be
hazardous to aquatic organisms in neighboring areas. Do not contaminate water
by cleaning of equipment or disposal of equipment wash waters.
This product is highly toxic to bees exposed to direct treatment on blooming
crops or weeds. Do not apply this product or allow it to drift to blooming crops or
weds while bees are actively visiting the treatment area.
Do not apply when winds speeds exceed 10 mph.
Environmental Fate This data was obtained using Permethrin, the active ingredient.
Log P: 6.10
Soil Absorption Koc: 277000
Hydrolysis HL, days: Stable (pH 5 and pH 7); 242 (pH 9)
Photolysis HL, days: 110 (water); 104 (soil)
Soil Deg HL, days: 39.5 (Aerobic); 197 (Anaerobic)
SECTION 13. DISPOSAL CONSIDERATIONS
General Disposal
Guidance
Pesticide Disposal: Wastes resulting from use of this product may be disposed of
on site or at an approved waste disposal facility.
Container Disposal CONTAINERS ONE GALLON OR SMALLER:
Do not reuse container. Wrap containers in several layers of newspaper and
discard in trash.
CONTAINERS LARGER THAN ONE GALLON
(Metal) Triple rinse or equivalent. Then offer for recycling or reconditioning or
puncture and dispose of in a sanitary landfill or by other approved State and
Local procedures.
(Plastic) Triple rinse or equivalent. Then offer for recycling or reconditioning or
puncture and dispose of in a sanitary landfill or incineration, or if allowed by
State and Local authorities, by burning. If burned, stay out of smoke.
SECTION 14. TRANSPORT INFORMATION
PROPER SHIPPING NAME: Not DOT regulated
SECTION 15. REGULATORY INFORMATION
US Federal
EPA Registration No. 432-1235
TSCA list
Piperonyl butoxide 51-03-6
TSCA 12b export notification
None
SARA Title III - section 302 - notification and information
None
SARA Title III - section 313 - toxic chemical release reporting
Permethrin 52645-53-1 1.0%
Piperonyl butoxide 51-03-6 1.0%
US States Regulatory
CA Prop65
This product contains a chemical known to the state of California to cause cancer.
None
This product contains a chemical known to the state of California to cause birth defects or other
reproductive harm.
None
US State right-to-know ingredients
Material Safety Data Sheet
MSDS Number: 1704
PERMANONE 30-30 MSDS Version 1.0
Permethrin 52645-53-1 NJ
Piperonyl butoxide 51-03-6 NJ
Canadian Regulations
Canadian Registrat. No.
Canadian Domestic Substance List
Piperonyl butoxide 51-03-6
Environmental
CERCLA
None
Clean Water Section 307 Priority Pollutants
None
Safe Drinking Water Act Maximum Contaminant Levels
None
International Regulations
EU Classification
None
European Inventory of Existing Commercial Substances (EINECS)
Permethrin 52645-53-1
Piperonyl butoxide 51-03-6
SECTION 16. OTHER INFORMATION
Health Flammability Reactivity Others
HMIS12 0 B
NFPA 1 2 0
REVISED SECTIONS: New MSDS.
Print Date: 01/08/2002
Supersedes MSDS, which is older than: 10/24/2001
This information is provided in good faith but without express or implied warranty. Buyer assumes
all
responsibility for safety and use not in accordance with label instructions. The product names are
registered
trademarks of Aventis.

Source: http://www.mcci.info/permanone.pdf