SAFETY DATA SHEET According to Safe Work Australia 1. IDENTIFICATION: PRODUCT IDENTIFIER AND CHEMICAL IDENTITY Product Name: POOL PRO LITHIUM Recommended Use of the Chemical and Restriction on Use: Swimming pool sanitiser Details of Manufacturer or Importer: The POPS Group Pty Ltd as Trustee for The Pool Shops Trust 10-12 Cairns Street Loganholme QLD 4129 Phone Number: 07 3209 7884 1800 143 788 Emergency telephone number: 1800 033 111 +61 3 9663 2130 International 2. HAZARDS IDENTIFICATION Hazardous Nature:
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Acute Tox. 4 H302 Harmful if swallowed. Label Elements Signal Word Danger Hazard Statements H272 May intensify fire; oxidiser. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. Precautionary Statements P221
Take any precaution to avoid mixing with combustibles.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Do not breathe dust/fume/gas/mist/vapours/spray.
Keep/Store away from clothing/combustible materials.
Wear protective gloves/protective clothing/eye protection/face protection.
Wash hands thoroughly after handling.
Do no eat, drink or smoke when using this product.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor/physician. SAFETY DATA SHEET According to Safe Work Australia Product Name: POOL PRO LITHIUM
Specific treatment (see on this label).
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable forbreathing.
Wash contaminated clothing before reuse.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P330
In case of fire: Use for extinction: CO2, powder or water spray.
Dispose of contents/container in accordance with local/regional/national regulations. Additional Information AUH031 Contact with acids liberates toxic gas. 3. COMPOSITION AND INFORMATION ON INGREDIENTS Chemical Characterization: Mixtures Description: Mixture of substances listed below with nonhazardous additions. Hazardous Components:
13840-33-0 Hypochlorous acid, lithium salt
4. FIRST AID MEASURES Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Seek immediate medical attention. Skin Contact: Remove contaminated clothing and wash affected areas with soap and water. Seek medical attention if symptoms develop. Launder clothing before reuse. Eye Contact: In case of eye contact, check for and remove any contact lenses. Immediately irrigate eyes with plenty of running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. Ingestion: Never give anything by mouth to an unconscious person. Immediately rinse mouth with water. If swallowed, do NOT induce vomiting. Give a glass of water. Seek immediate medical attention. Information for Doctor Product is an eye errant and corrosive to the skin. Treatment goal is dilution and removal. Gastric lavage may be useful for ingestion exposure as emesis may produce esophageal damage. Treatment is otherwise symptomatic and supportive. 5. FIRE FIGHTING MEASURES Suitable Extinguishing Media: Use extinguishing media suitable for the surrounding fire Specific Hazards Arising from the Chemical Decomposes slowly in water with the evolution of chlorine gas. Non-combustible but accelerates the burning of combustible material. Prolonged exposure of closed containers to heat may result in vigorous decomposition and rupture of the container. It will react explosively with hydrocarbons (fuels). Special Protective Equipment and Precautions for Fire Fighters Wear Safe Work Australia approved self-contained breathing apparatus and full protective clothing. SAFETY DATA SHEET According to Safe Work Australia Product Name: POOL PRO LITHIUM 6. ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures: Wear Safe Work Australia approved self contained breathing apparatus and full protective clothing. Evacuate all non-essential personnel from affected area. Ensure adequate ventilation. Do not breathe dust. Environmental Precautions: In the event of a major spill, prevent spillage from entering drains or water courses. Methods and Materials for Containment and Cleaning Up: Stop leak if safe to do so and contain spill. Vacuum or wet sweep spilled material and place in an appropriate container for disposal. Avoid generating dust. Using non sparking tools. Do not close containers containing wet or damp material. They should be left open to disperse any hazardous gases that may form. 7. HANDLING AND STORAGE Precautions for Safe Handling: Use of safe work practices are recommended to avoid eye or skin contact and inhalation of dust. Food, beverages and tobacco products should not be stored or consumed where this material is in use. Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and other protective equipment before storage or re-use. Provide eyewash fountains and safety showers in close proximity to points of potential exposure. Conditions for Safe Storage: Store in a cool, dry, well ventilated place and out of direct sunlight. Keep containers closed when not in use. Protect from heat and moisture (water). Keep away from acids, urea and ammonia. Check regularly for spills. 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Exposure Standards (Safe Work Australia): The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Engineering Contols: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapour below occupational exposure standards. Personal Protective Equipment (PPE): Respiratory Protection: Not necessary if engineering controls maintain airborne concentrations low. Use an Safe Work Australia approved full face supplied air respirator if high airborne concentrations of the material are present. See Australian Standards AS/NZS 1715 and 1716 for more information. Skin Protection: Impervious gloves, protective clothing, chemical resistant apron and safety boots. See Australian Standards AS/NZS 2161, 2210.1 and 2210.2 for more information. Eye and Face Protection: Safety glasses with top and side shields or goggles. See Australian Standards AS/NZS 1336 and 1337 for more information. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: SAFETY DATA SHEET According to Safe Work Australia Product Name: POOL PRO LITHIUM Odour Threshold: pH-Value: Melting point/Melting range: Initial Boiling Point/Boiling Range: Flash Point: Flammability:
Non-combustible but accelerates the burning of combustiblematerial. Auto-ignition Temperature: Decomposition Temperature: Explosion Limits: Vapour Pressure: Relative Density: Vapour Density: Evaporation Rate: Solubility in Water at 25 °C: Partition Coefficient (n-octanol/water): No information available Viscosity: % Volatiles by Volume: 10 . STABILITY AND REACTIVITY Possibility of Hazardous Reactions: Hazardous polymerisation will not occur. Chemical Stability: Stable at ambient temperature and under normal conditions of use. Conditions to Avoid: Extreme heat and moisture. Incompatible Materials: Acids, oxidizing materials. Forms highly explosive NCl3 on contact with urea or ammonia. When heated or on contact with acids, produces highly toxic fumes of chlorine gas. Hazardous Decomposition Products: Toxic chlorine gases. 11 . TOXICOLOGICAL INFORMATION Toxicity: LD₅₀/LC₅₀ Values Relevant for Classification: No information available Acute Health Effects Inhalation: Inhalation of dust can cause irritation or burns to the nose, throat and mucous membranes. Fine dust reaching the lungs is toxic. Skin: Contact with skin will result in severe irritation and may cause skin burns. Eye: A severe eye irritant. Contamination of eyes can result in permanent injury and blindness. Ingestion: Harmful if swallowed. Swallowing can cause burns to the mouth, throat and stomach resulting in vomiting, diarrhea and abdominal pain. Skin Corrosion / Irritation: Causes severe skin burns. Serious Eye Damage / Irritation: Causes eye damage. Respiratory or Skin Sensitisation: Not expected to be a hazard. Germ Cell Mutagenicity: No information available SAFETY DATA SHEET According to Safe Work Australia Product Name: POOL PRO LITHIUM Carcinogenicity: Not expected to be a hazard. Reproductive Toxicity: No information available Specific Target Organ Toxicity (STOT) - Single Exposure: No information available Specific Target Organ Toxicity (STOT) - Repeated Exposure: No information available Aspiration Hazard: No information available Chronic Health Effects: Irreversible eye damage, which may lead to blindness and skin burns. Existing Conditions Aggravated by Exposure: No information available 12 . ECOLOGICAL INFORMATION Ecotoxicity: No information available Persistence and Degradability: No information available Bioaccumulative Potential: No information available Mobility in Soil: No information available 13 . DISPOSAL CONSIDERATIONS Disposal Methods and Containers: Dispose according to applicable local and state government regulations. Special Precautions for Landfill or Incineration: Please consult your state Land Waste Management Authority for more information. 14 . TRANSPORT INFORMATION UN Number ADG, IMDG, IATA Proper Shipping Name ADG, IMDG, IATA Dangerous Goods Class ADG Class: Packing Group: ADG, IMDG, IATA Hazchem Code: Special Provisions: Limited Quantities: Packagings & IBCs - Packing Instruction: Packagings & IBCs - Special Packing Provisions: B2, B4 Portable Tanks & Bulk Contatiners - Instructions: Not applicable Portable Tanks & Bulk Containers - Special Provisions: 15 . REGULATORY INFORMATION Australian Inventory of Chemical Substances:
13840-33-0 Hypochlorous acid, lithium salt
SAFETY DATA SHEET According to Safe Work Australia Product Name: POOL PRO LITHIUM Standard for the Uniform Scheduling of Drugs and Poisons (SUSMP) - Poison Schedule: Poisons Schedule: 5 16 . OTHER INFORMATION Creation Date: 17.06.2013 Last Revision of MSDS: Rev 1.1 (16/06/2008) Prepared by: MSDS.COM.AU Pty Ltd www.msds.com.au Abbreviations and acronyms: ADG: Australian Dangerous Goods IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals VOC: Volatile Organic Compounds LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent IARC: International Agency for Research on Cancer Disclaimer This MSDS is prepared in accord with the Safe Work Australia document “Code of Practice for the Preparation of Safety Data Sheets for Hazardous Chemicals - December 2011” The information contained in this material safety data sheet is provided in good faith and is believed to be accurate at the date of issuance. The POPS Group Pty Ltd as Trustee for The Pool Shops Trust makes no representation of the accuracy or comprehensiveness of the information and to the full extent allowed by law excludes all liability for any loss or damage related to the supply or use of the information in this material safety data sheet. MSDS.COM.AU Pty Ltd is not in a position to warrant the accuracy of the data herein. The user is cautioned to make their own determinations as to the suitability of the information provided to the particular circumstances in which the product is used.
Zbigniew Barszcz1, Jolanta Rabe-Jab³oñska2Zaburzenia wydzielania prolaktyny w trakcie stosowania lekówpsychotropowych innych ni¿ leki przeciwpsychotyczneDisturbances of prolactin secreting during treatment with psychotropicdrugs other than antipsychotics1 Centralny Szpital Kliniczny Uniwersytetu Medycznego w £odzi2 Katedra Psychiatrii Uniwersytetu Medycznego w £odziCorrespondence to: Zbign