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FUJIFILM SERICOL ADVANTAGE ON METATRAN ADHESIVE ON421
Chemwatch Independent Material Safety Data Sheet
Issue Date: 9-Dec-2009
CHEMWATCH 15-8947
XCC317TCP
Version No:2.0
CD 2010/1 Page 1 of 9
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
FUJIFILM SERICOL ADVANTAGE ON METATRAN ADHESIVE ON421
PRODUCT USE
Screen making adhesive.
SUPPLIER
Company: FUJIFILM Australia Pty Ltd
Address:
114 Old Pittwater Road
Brookvale
NSW, 2100
AUS
Telephone: +61 2 9466 2600
Emergency Tel: +61 1800 039 008
Emergency Tel: +61 3 9573 3112
Fax: +61 2 9938 1975
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.
CHEMWATCH HAZARD RATINGS
POISONS SCHEDULE
¦ Do not breathe gas/ fumes/ vapour/ spray.
system and skin.
¦ May cause SENSITISATION by ¦ Avoid exposure - obtain special instructions before use.
inhalation and skin contact.
¦ May cause long- term adverse ¦ To clean the floor and all objects contaminated by this ¦ Keep away from food drink and animal feeding stuffs.
if swallowed.
¦ Ingestion may produce health ¦ In case of contact with eyes rinse with plenty of water and contact Doctor or Poisons Information Centre.
¦ If swallowed IMMEDIATELY contact Doctor or Poisons Information Centre (show this container or label).
¦ Limited evidence of acarcinogenic effect*.
¦ May possibly affect fertility*.
continued.
FUJIFILM SERICOL ADVANTAGE ON METATRAN ADHESIVE ON421
Chemwatch Independent Material Safety Data Sheet
Issue Date: 9-Dec-2009
CHEMWATCH 15-8947
XCC317TCP
Version No:2.0
CD 2010/1 Page 2 of 9
Section 2 - HAZARDS IDENTIFICATION
¦ May possibly be harmful to thefoetus/ embryo*.
* (limited evidence).
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
Section 4 - FIRST AID MEASURES
SWALLOWED
• If swallowed do NOT induce vomiting.
• If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
• Observe the patient carefully.
• Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
• If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible aspiration of vomitus.
EYE
¦ If this product comes in contact with the eyes:
• Wash out immediately with fresh running water.
• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower
lids.
• Seek medical attention without delay; if pain persists or recurs seek medical attention.
• Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
SKIN
¦ If skin contact occurs:
• Immediately remove all contaminated clothing, including footwear.
• Flush skin and hair with running water (and soap if available).
• Seek medical attention in event of irritation.
INHALED
• If fumes or combustion products are inhaled remove from contaminated area.
• Lay patient down. Keep warm and rested.
• Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
• Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained.
Perform CPR if necessary.
NOTES TO PHYSICIAN
¦ Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or pharmacologically.
Mechanical means should be used if it is considered necessary to evacuate the stomach contents; these include gastric lavage after endotracheal
intubation. If spontaneous vomiting has occurred after ingestion, the patient should be monitored for difficult breathing, as adverse effects of
aspiration into the lungs may be delayed up to 48 hours.
Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
• There is no restriction on the type of extinguisher which may be used.
• Use extinguishing media suitable for surrounding area.
FIRE FIGHTING
• Alert Fire Brigade and tell them location and nature of hazard.
• Wear breathing apparatus plus protective gloves for fire only.
• Prevent, by any means available, spillage from entering drains or water courses.
• Use fire fighting procedures suitable for surrounding area.
• DO NOT approach containers suspected to be hot.
• Cool fire exposed containers with water spray from a protected location.
• If safe to do so, remove containers from path of fire.
• Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
¦ other pyrolysis products typical of burning organic material.
May emit poisonous fumes.
May emit corrosive fumes.
• Non combustible.
continued.
FUJIFILM SERICOL ADVANTAGE ON METATRAN ADHESIVE ON421
Chemwatch Independent Material Safety Data Sheet
Issue Date: 9-Dec-2009
CHEMWATCH 15-8947
XCC317TCP
Version No:2.0
CD 2010/1 Page 3 of 9
Section 5 - FIRE FIGHTING MEASURES
• Not considered a significant fire risk, however containers may burn.
Decomposition may produce toxic fumes of: FIRE INCOMPATIBILITY
• Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.
Personal Protective Equipment
Limit exposure duration to 1 BA set 30 mins.
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
¦ Environmental hazard - contain spillage.
• Clean up all spills immediately.
• Avoid breathing vapours and contact with skin and eyes.
• Control personal contact by using protective equipment.
• Contain and absorb spill with sand, earth, inert material or vermiculite.
• Wipe up.
• Place in a suitable, labelled container for waste disposal.
MAJOR SPILLS
¦ Environmental hazard - contain spillage.
Moderate hazard.
• Clear area of personnel and move upwind.
• Alert Fire Brigade and tell them location and nature of hazard.
• Wear breathing apparatus plus protective gloves.
• Prevent, by any means available, spillage from entering drains or water course.
• Stop leak if safe to do so.
• Contain spill with sand, earth or vermiculite.
• Collect recoverable product into labelled containers for recycling.
• Neutralise/decontaminate residue.
• Collect solid residues and seal in labelled drums for disposal.
• Wash area and prevent runoff into drains.
• After clean up operations, decontaminate and launder all protective clothing and equipment before storing and re-using.
• If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
• DO NOT allow clothing wet with material to stay in contact with skin.
• Avoid all personal contact, including inhalation.
• Wear protective clothing when risk of exposure occurs.
• Use in a well-ventilated area.
• Avoid contact with moisture.
• Avoid contact with incompatible materials.
• When handling, DO NOT eat, drink or smoke.
• Keep containers securely sealed when not in use.
• Avoid physical damage to containers.
• Always wash hands with soap and water after handling.
• Work clothes should be laundered separately. Launder contaminated clothing before re-use.
• Use good occupational work practice.
• Observe manufacturer's storing and handling recommendations.
• Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained.
SUITABLE CONTAINER
• Polyethylene or polypropylene container.
• Packing as recommended by manufacturer.
• Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
• Avoid reaction with oxidising agents.
STORAGE REQUIREMENTS
• Store in original containers.
• Keep containers securely sealed.
• Store in a cool, dry, well-ventilated area.
• Store away from incompatible materials and foodstuff containers.
continued.
FUJIFILM SERICOL ADVANTAGE ON METATRAN ADHESIVE ON421
Chemwatch Independent Material Safety Data Sheet
Issue Date: 9-Dec-2009
CHEMWATCH 15-8947
XCC317TCP
Version No:2.0
CD 2010/1 Page 4 of 9
Section 7 - HANDLING AND STORAGE
• Protect containers against physical damage and check regularly for leaks.
• Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
The following materials had no OELs on our records
• bis(methylcyclohexyl)phthalate:
PERSONAL PROTECTION
RESPIRATOR
Type A-P Filter of sufficient capacity
EYE
• Safety glasses with side shields.
• Chemical goggles.
• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the
wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption andadsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in theirremoval and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contactlens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environmentonly after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
• Wear chemical protective gloves, eg. PVC.
• Wear safety footwear or safety gumboots, eg. Rubber.
NOTE:
• The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protective equipment, to
• Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.
Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include: such as:• frequency and duration of contact,• chemical resistance of glove material,• glove thickness and• dexteritySelect gloves tested to a relevant standard (e.g. Europe EN 374, US F739).
• When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN 374) is recommended.
• When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to EN 374) • Contaminated gloves should be replaced.
Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturiseris recommended.
OTHER
• Overalls.
• P.V.C. apron.
• Barrier cream.
• Skin cleansing cream.
• Eye wash unit.
ENGINEERING CONTROLS
¦ Local exhaust ventilation usually required. If risk of overexposure exists, wear approved respirator. Correct fit is essential to obtain adequate
protection. Supplied-air type respirator may be required in special circumstances. Correct fit is essential to ensure adequate protection.
An approved self contained breathing apparatus (SCBA) may be required in some situations.
Provide adequate ventilation in warehouse or closed storage area. Air contaminants generated in the workplace possess varying "escape" velocities
which, in turn, determine the "capture velocities" of fresh circulating air required to effectively remove the contaminant.
solvent, vapours, degreasing etc., evaporating continued.
FUJIFILM SERICOL ADVANTAGE ON METATRAN ADHESIVE ON421
Chemwatch Independent Material Safety Data Sheet
Issue Date: 9-Dec-2009
CHEMWATCH 15-8947
XCC317TCP
Version No:2.0
CD 2010/1 Page 5 of 9
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
intermittent container filling, low speedconveyer transfers, welding, spray drift,plating acid fumes, pickling (released at lowvelocity into zone of active generation)direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts,gas discharge (active generation into zone ofrapid air motion)grinding, abrasive blasting, tumbling, high speed wheel generated dusts (released at highinitial velocity into zone of very high rapidair motion).
Within each range the appropriate value depends on: 1: Room air currents minimal or favourable to capture2: Contaminants of low toxicity or of nuisance value only.
3: Intermittent, low production.
4: Large hood or large air mass in motion Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally decreaseswith the square of distance from the extraction point (in simple cases). Therefore the air speed at the extraction point should be adjusted,accordingly, after reference to distance from the contaminating source. The air velocity at the extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min) for extraction of solvents generated in a tank 2 meters distant from the extraction point. Other mechanical considerations,producing performance deficits within the extraction apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 ormore when extraction systems are installed or used.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Coloured liquid with a characteristic odour; does not mix with water.
PHYSICAL PROPERTIES
Liquid.
Does not mix with water.
Sinks in water.
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
• Presence of incompatible materials.
• Product is considered stable.
• Hazardous polymerisation will not occur.
For incompatible materials - refer to Section 7 - Handling and Storage.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
¦ May cause SENSITISATION by inhalation and skin continued.
FUJIFILM SERICOL ADVANTAGE ON METATRAN ADHESIVE ON421
Chemwatch Independent Material Safety Data Sheet
Issue Date: 9-Dec-2009
CHEMWATCH 15-8947
XCC317TCP
Version No:2.0
CD 2010/1 Page 6 of 9
Section 11 - TOXICOLOGICAL INFORMATION
¦ Irritating to eyes, respiratory system and ¦ Limited evidence of a carcinogenic effect*.
skin.
¦ Ingestion may produce health damage*.
¦ May possibly be harmful to the foetus/embryo*.
¦ Cumulative effects may result followingexposure*.
¦ * (limited evidence).
TOXICITY AND IRRITATION
BIS(2-ETHYLHEXYL) MALEATE:
AZODICARBONAMIDE:
BIS(METHYLCYCLOHEXYL)PHTHALATE:
¦ unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
BIS(2-ETHYLHEXYL) MALEATE:BIS(METHYLCYCLOHEXYL)PHTHALATE:¦ The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production ofvesicles, scaling and thickening of the skin.
¦ The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to irritants may produceconjunctivitis.
¦ Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-allergenic conditionknown as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating compound. Key criteriafor the diagnosis of RADS include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence ofmoderate to severe bronchial hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia,have also been included in the criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalation is an infrequent disorder withrates related to the concentration of and duration of exposure to the irritating substance. Industrial bronchitis, on the other hand, is a disorderthat occurs as result of exposure due to high concentrations of irritating substance (often particulate in nature) and is completely reversible afterexposure ceases. The disorder is characterised by dyspnea, cough and mucus production.
¦ unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
¦ Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-allergenic conditionknown as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating compound. Key criteriafor the diagnosis of RADS include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence ofmoderate to severe bronchial hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia,have also been included in the criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalation is an infrequent disorder withrates related to the concentration of and duration of exposure to the irritating substance. Industrial bronchitis, on the other hand, is a disorderthat occurs as result of exposure due to high concentrations of irritating substance (often particulate in nature) and is completely reversible afterexposure ceases. The disorder is characterised by dyspnea, cough and mucus production.
Allergic reactions involving the respiratory tract are usually due to interactions between IgE antibodies and allergens and occur rapidly. Allergicpotential of the allergen and period of exposure often determine the severity of symptoms. Some people may be genetically more prone than others, andexposure to other irritants may aggravate symptoms. Allergy causing activity is due to interactions with proteins.
Attention should be paid to atopic diathesis, characterised by increased susceptibility to nasal inflammation, asthma and eczema.
Exogenous allergic alveolitis is induced essentially by allergen specific immune-complexes of the IgG type; cell-mediated reactions (T lymphocytes)may be involved. Such allergy is of the delayed type with onset up to four hours following exposure.
The material may produce peroxisome proliferation. Peroxisomes are single, membrane limited organelles in the cytoplasm that are found in the cellsof animals, plants, fungi, and protozoa. Proxisome proliferators include certain hypolipidaemic drugs, phthalate ester plasticisers, industrialsolvents, herbicides, food flavours, leukotriene D4 antagonists and hormones. Animal studies have shown that peroxisome proliferators clearly causecancer, especially of the liver.
The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to irritants may produceconjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production ofvesicles, scaling and thickening of the skin.
¦ The material may produce peroxisome proliferation. Peroxisomes are single, membrane limited organelles in the cytoplasm that are found in the cellsof animals, plants, fungi, and protozoa. Proxisome proliferators include certain hypolipidaemic drugs, phthalate ester plasticisers, industrialsolvents, herbicides, food flavours, leukotriene D4 antagonists and hormones. Animal studies have shown that peroxisome proliferators clearly causecancer, especially of the liver.
No significant acute toxicological data identified in literature search.
Intraperitoneal (rat) LD50: >5000 mg/kg Intraperitoneal (mouse) LD50: >1000 mg/kg Dermal (rabbit) LD50: 15 ml/kg¦ For Group B aliphatic esters of mono-alcohols and diacids (diesters)According to a classification scheme described by the American Chemistry Council' Aliphatic Esters Panel, Group B substances are comprised ofaliphatic esters derived from linear diacids and monofunctional alcohols. The diacids include maleic (C4), adipic (C6), azelaic (C9) and sebacic(C10) acid. The monofunctional alcohols most common in the diesters are in the C8 to C13 carbon range, although methyl, isopropyl and butyl occur insome diesters.
Due to the physicochemical properties of the diesters (e.g., viscosity, pour point), they have widespread applications as lubricants, solvents, andplasticisers. The linear diacid portion of the diester contributes to the good viscosity index while branching in the alcohol portion provides goodpour point characteristics. Because diesters have good polarity characteristics, they are useful as solvents.
continued.
FUJIFILM SERICOL ADVANTAGE ON METATRAN ADHESIVE ON421
Chemwatch Independent Material Safety Data Sheet
Issue Date: 9-Dec-2009
CHEMWATCH 15-8947
XCC317TCP
Version No:2.0
CD 2010/1 Page 7 of 9
Section 11 - TOXICOLOGICAL INFORMATION
Acute toxicity: Most of the diesters in Group B are higher alkyl (>C8) adipates, azelates and sebacates and these diesters generally have a low orderof toxicity. Oral rat LD50 values ranged from >2 g/kg to >64 g/kg.
Metabolism of the diesters in animals is expected to lead to the generation of corresponding diacids: namely, maleic, adipic, azelaic and sebacicacid and the corresponding linear or branched alcohol (e.g., 2-ethylhexyl, I-methylheptyl, isooctyl, isononyl, isodecyl, tridecyl alcohols). Thesediacids and alcohols can further be metabolized and conjugated to products that are excreted in the urine The diacids and alcohols have a low order of toxicityRepeated Dose Toxicity. Data on repeated dose toxicity have been reported for diisononyl adipate and tridecyl adipate. In 90-day toxicity studies,rats were administered diisononyl adipate (CAS 33703-08-l) in the diet at levels equivalent to 0,50, 150 and 500 mg/kg/day. The NOAEL was 500mg/kg/day. Feeding studies were also carried out in beagle dogs for 13 weeks at dietary concentrations of 0,0.3, 1 and 3% (increased to 6% at week9). The NOAEL was determined to be 1% in the diet or approximately 274 mg/kg/day. In another 13-week study, ditridecyl adipate was well tolerated inrats given dermal doses of 800 and 2000 mg/kg/day.
For adipic acid di-C7-9 branched and linear alkyl ester (CAS 685 15-75-3), rats were fed 0,O. 1,0.5 and 2.5% of the test substance in the diet. Nosignificant signs of toxicity were observed in male and female rats administered the test material in the diet at concentrations up to 2.5% for aperiod of 13 weeks. The NOAEL was 2.5% for both sexes (males -1300 mg/kg; females -1800 mg/kg). In the 90-day dietary studies with 2-ethylhexyladipate (CAS 103-23-l), the NOAEL was -300 mg/kg/day in rats and -230 mg/kg/day in mice. The LOAEL was -600 mg/kg/day in rats and -460 mg/kg/day inmice. Hepatic hypertrophy and increased peroxisomal enzyme activity occurred in rats and mice; however, there were no adverse effects on the liver.
Reproductive toxicity: Di-2-ethylhexyl adipate (DEHA)(CAS 103-23-l) has been evaluated for reproductive effects in a one-generation study. Test diets,up to 1080 mg/kg/day, were fed continuously throughout the study (18-19 weeks of exposure). No effects were seen on male or female fertility.
However, at the highest dose, there was a reduction in body weight in the dams, and reduction in offspring body weight, total litter weight andlitter size. The NOAEL and LOAEL for this study was 170 and 1080 mg/kg/day, respectively. In 13-week dermal studies with ditridecyl adipate, therewas no sperm morphological changes observed in male rats treated at levels of 2000 mg/kg. Increases in organ weight of the epididymides and uteruswere observed at dermal exposure to 2000 mg/kg but not at 800 mg/kg. In a 19-week oral feeding study with sebacic acid, bis(2-ethylhexyl) ester (CAS122~62-3), no adverse reproductive effects were reported for this material. Dibutyl maleate has been evaluated in an OECD reproductive/developmentaltoxicity screening test (oral gavage) and no adverse effects on reproduction were reported.
Since these four materials cover the carbon number range of C12-C32 for the diesters and because of the chemical similarity of the alkyl diesters,the available reproductive toxicity data should be sufficient for read-across assessment of most of the other diesters in Group B.
Developmental toxicity: No evidence of developmental toxicity was observed at dose levels of 1000 and 4000 mg/kg/day after oral gavage of adipic acid,di-C7-9 branched and linear alkyl ester (CAS 685 15-75-3). Slight maternal toxicity (reduced body weight) and embryotoxicity (reduced foetal weight)was observed at the highest dose (7000 mg/kg/day). The NOAEL for maternal and developmental toxicity was 4000 mg/kg/day. No adverse developmentaleffects were reported for dibutyl maleate in an OECD reproductive/developmental screening studyThe developmental toxicity has also been evaluated for adipic acid, bis(2-ethylhexyl) ester (CAS 103-23-l) by dietary exposure. Pregnant ratsadministered 2-ethylhexyl adipate in the diet throughout gestation showed reduced body weight at dietary equivalent doses of 1080 mg/kg/day. At 1080mg/kg/day, implantation fetal loss was evident; however, no gross, skeletal or visceral abnormalities were observed. LOAEL was 1080 mg/kg/day andNOAEL was 170 mg/kg/day (developmental toxicity). The developmental toxicity data from these three studies provide sufficient data for the read-across assessment of most of the other diesters in Group B due to their chemical structural similarities.
Genotoxicity: Adipic acid diisononyl ester and sebacic acid bis(2-ethylhexyl) ester] were shown to be negative in the Ames assay. In addition,diisononyl adipate was negative in the mouse lymphoma assay. Adipic acid, bis(2-ethylhexyl) ester has also been evaluated for mutagenicity and was found to be negative in both the Ames and mouse lymphoma assays. It has also been reported that dibutyl maleate (CAS 105- 76-0) is negative in theAmes assayAdipic acid, ditridecyl ester (CAS 16958-92-2) was negative in the micronucleus assay. Adipic acid bis(2- ethylhexyl) ester (CAS 103-23-l), also didnot cause chromosomal aberrations in the Chinese hamster ovary cell assay or the mouse micronucleus test . Since these two adipates cover the carbonnumber range of C22-C32 for the diesters, it is unlikely that the substances in Group B are chromosomal mutagens. In addition, dibutyl maleate (C12)has been shown to be negative in the mouse micronucleus test in vivo.
¦ Allergic reactions involving the respiratory tract are usually due to interactions between IgE antibodies and allergens and occur rapidly. Allergicpotential of the allergen and period of exposure often determine the severity of symptoms. Some people may be genetically more prone than others, andexposure to other irritants may aggravate symptoms. Allergy causing activity is due to interactions with proteins.
Attention should be paid to atopic diathesis, characterised by increased susceptibility to nasal inflammation, asthma and eczema.
Exogenous allergic alveolitis is induced essentially by allergen specific immune-complexes of the IgG type; cell-mediated reactions (T lymphocytes)may be involved. Such allergy is of the delayed type with onset up to four hours following exposure.
Section 12 - ECOLOGICAL INFORMATION
May cause long-term adverse effects in the environment.
Ecotoxicity
Ingredient
continued.
FUJIFILM SERICOL ADVANTAGE ON METATRAN ADHESIVE ON421
Chemwatch Independent Material Safety Data Sheet
Issue Date: 9-Dec-2009
CHEMWATCH 15-8947
XCC317TCP
Version No:2.0
CD 2010/1 Page 8 of 9
Section 13 - DISPOSAL CONSIDERATIONS
• Containers may still present a chemical hazard/ danger when empty.
• Return to supplier for reuse/ recycling if possible.
Otherwise:• If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.
• Where possible retain label warnings and MSDS and observe all notices pertaining to the product.
Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in their area. In some areas, certain wastes must be tracked.
A Hierarchy of Controls seems to be common - the user should investigate:• Reduction• Reuse• Recycling• Disposal (if all else fails)This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. If it has been contaminated, it may be possible to reclaim the product by filtration, distillation or some other means. Shelf life considerations should also be applied in making decisions of this type. Note that properties of a material may change in use, and recycling or reuse may not always be appropriate.
• DO NOT allow wash water from cleaning or process equipment to enter drains.
• It may be necessary to collect all wash water for treatment before disposal.
• In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
• Where in doubt contact the responsible authority.
• Recycle wherever possible.
• Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified.
• Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or incineration in a licenced apparatus (after admixture with suitable combustible material).
• Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.
Section 14 - TRANSPORTATION INFORMATION
HAZCHEM:
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: UN, IATA, IMDG Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE
REGULATIONS
Regulations for ingredients
bis(methylcyclohexyl)phthalate (CAS: 27987-25-3) is found on the following regulatory lists;
"Australia Inventory of Chemical Substances (AICS)"
bis(2-ethylhexyl) maleate (CAS: 142-16-5) is found on the following regulatory lists;
"Australia Inventory of Chemical Substances (AICS)","International Council of Chemical Associations (ICCA) - High Production Volume List","OECD
Representative List of High Production Volume (HPV) Chemicals"
azodicarbonamide (CAS: 123-77-3) is found on the following regulatory lists;
"Australia Dangerous Goods Code (ADG Code) - List of Currently Assigned Self-Reactive Substances in Packagings","Australia Hazardous Substances",
"Australia Inventory of Chemical Substances (AICS)","International Air Transport Association (IATA) Dangerous Goods Regulations","International Air
Transport Association (IATA) Dangerous Goods Regulations - Prohibited List","OECD Representative List of High Production Volume (HPV) Chemicals"
No data for Fujifilm Sericol Advantage On Metatran Adhesive ON421 (CW: 15-8947)
Section 16 - OTHER INFORMATION
Denmark Advisory list for selfclassification of dangerous substances
Substance
¦ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.
continued.
FUJIFILM SERICOL ADVANTAGE ON METATRAN ADHESIVE ON421
Chemwatch Independent Material Safety Data Sheet
Issue Date: 9-Dec-2009
CHEMWATCH 15-8947
XCC317TCP
Version No:2.0
CD 2010/1 Page 9 of 9
Section 16 - OTHER INFORMATION
A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references.
¦ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 9-Dec-2009Print Date: 23-May-2010

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