Sdb_141_(gb)_

Safety data sheet
according to 1907/2006/EC, Article 31
1 Identification of the substance/mixture and of the company/undertaking
· Product identifier
· Trade name: Renovan Silberreinigungsbad
Renova silver cleaning bath
· Article number: 3130401002
· Relevant identified uses of the substance or mixture and uses advised against
· Application of the substance / the preparation
Metal surface treatmentCleaning material/ Detergent · Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Wieland Edelmetalle GmbHSchwenninger Str. 1375179 PforzheimTelefon +49 (07231)-1393-0, Telefax +49 (07231)-1393-100 · Further information obtainable from:
Wieland Edelmetalle GmbHwww.wieland-edelmetalle.de · Emergency telephone number:
GIZ-Nord, Göttingen, Germany+49 551 19240Member of EPECS Network 2 Hazards identification
· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
H361d Suspected of damaging the unborn child.
Causes severe skin burns and eye damage.
Harmful to aquatic life with long lasting effects.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Limited evidence of a carcinogenic effect.
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
· Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literaturedata.
Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: Renovan Silberreinigungsbad
Renova silver cleaning bath
· Label elements
· Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on HazardousMaterials.
· Code letter and hazard designation of product:
· Hazard-determining components of labelling:
· Risk phrases:
Limited evidence of a carcinogenic effect.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
· Safety phrases:
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label wherepossible).
This material and its container must be disposed of as hazardous waste.
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
Skin Irrit. 2, H315; Eye Irrit. 2, H319; Aquatic Chronic 3, H412 4 First aid measures
· Description of first aid measures
· General information: Immediately remove any clothing soiled by the product.
Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: Renovan Silberreinigungsbad
Renova silver cleaning bath
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions.
· Special hazards arising from the substance or mixture
In case of fire, the following can be released:Sulphur dioxide (SO2) · Advice for firefighters
· Protective equipment: Mount respiratory protective device.
6 Accidental release measures
· Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
· Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
· Handling:
· Precautions for safe handling Keep receptacles tightly sealed.
· Information about fire - and explosion protection: No special measures required.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep receptacle tightly sealed.
· Specific end use(s) No further relevant information available.
8 Exposure controls/personal protection
· Additional information about design of technical facilities: No further data; see item 7.
Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: Renovan Silberreinigungsbad
Renova silver cleaning bath
· Control parameters
· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitoredat the workplace.
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothingWash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Respiratory protection:
Use suitable respiratory protective device in case of insufficient ventilation.
B-P3 · Protection of hands:
· Material of gloves
Butyl rubber, BRFluorocarbon rubber (Viton)Nitrile rubber, NBRChloroprene rubber, CR · Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to beobserved.
· Eye protection:
· Body protection: Protective work clothing
9 Physical and chemical properties
· Information on basic physical and chemical properties
· General Information
· Appearance:
· Odour:
· pH-value at 20°C:
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 105°C
· Flash point:
· Self-igniting:
· Danger of explosion:
Product does not present an explosion hazard.
Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: Renovan Silberreinigungsbad
Renova silver cleaning bath
· Explosion limits:
Oxidizing properties
· Density at 20°C:
· Solubility in / Miscibility with
· Solvent content:
Organic solvents:
· Other information
No further relevant information available.
10 Stability and reactivity
· Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: Sulphur oxides (SOx)
11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values relevant for classification:
7664-93-9 sulphuric acid
62-56-6 thiourea
· Primary irritant effect:
· on the skin: Strong caustic effect on skin and mucous membranes.
· on the eye: Strong caustic effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU ClassificationGuidelines for Preparations as issued in the latest version:CorrosiveHarmful 12 Ecological information
· Toxicity
· Acquatic toxicity:
7664-93-9 sulphuric acid
LC50 42 mg/l (96h) (Gambusia affinis (Mosquitofish)) · Persistence and degradability No further relevant information available.
Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: Renovan Silberreinigungsbad
Renova silver cleaning bath
· Behaviour in environmental systems:
· Bioaccumulative potential
No further relevant information available.
No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for waterDo not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation Must be specially treated adhering to official regulations.
· European waste catalogue
11 00 00 WASTES FROM CHEMICAL SURFACE TREATMENT AND COATING OF METALS AND OTHER MATERIALS; NON-FERROUS HYDRO-METALLURGY 11 01 00 wastes from chemical surface treatment and coating of metals and other materials (for example galvanic processes, zinc coating processes, pickling processes, etching, phosphating, alkalinedegreasing, anodising) · Uncleaned packaging:
· Recommendation:
Empty contaminated packagings thoroughly. They may be recycled after thorough and proper cleaning.
Packagings that may not be cleansed are to be disposed of in the same manner as the product.
· Recommended cleansing agents: Water, if necessary together with cleansing agents.
14 Transport information
· UN-Number
· ADR, IMDG, IATA
· UN proper shipping name
· ADR
3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.
(SULPHURIC ACID, SULPHAMIC ACID) · IMDG, IATA
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.
(SULPHURIC ACID, SULPHAMIC ACID) · Transport hazard class(es)
Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: Renovan Silberreinigungsbad
Renova silver cleaning bath
· IMDG, IATA
· Packing group
· ADR, IMDG, IATA
· Environmental hazards:
· Marine pollutant:
· Special precautions for user
· Danger code (Kemler):
· EMS Number:
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
· Transport/Additional information:
· ADR
· Limited quantities (LQ)
· Transport category
· Tunnel restriction code
· UN "Model Regulation":
UN3264, CORROSIVE LIQUID, ACIDIC, INORGANIC,N.O.S., 8, III 15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· National regulations:
· Technical instructions (air):
Class Share in %
· Waterhazard class: Water hazard class 2 (Self-assessment): hazardous for water.
· Chemical safety assessment: A Chemical Safety Assessment has been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for anyspecific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
Causes severe skin burns and eye damage.
H361d Suspected of damaging the unborn child.
H411 Toxic to aquatic life with long lasting effects.
Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: Renovan Silberreinigungsbad
Renova silver cleaning bath
Harmful to aquatic life with long lasting effects.
R36/38 Irritating to eyes and skin.
R40 Limited evidence of a carcinogenic effect.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R63 Possible risk of harm to the unborn child.
· Department issuing MSDS: Abteilung Umweltschutz
· Contact: Herr Marcus Müller
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the InternationalCarriage of Dangerous Goods by Road)RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning theInternational Transport of Dangerous Goods by Rail)IMDG: International Maritime Code for Dangerous GoodsIATA: International Air Transport AssociationICAO: International Civil Aviation OrganizationGHS: Globally Harmonized System of Classification and Labelling of ChemicalsLC50: Lethal concentration, 50 percentLD50: Lethal dose, 50 percent · * Data compared to the previous version altered.

Source: http://www.wieland-edelmetalle.de/uploads/tx_pxwldownloads/SDB_141__GB__.pdf