Microsoft word - msds_liquid_oleum_inggris.doc

Office & Factory : Jalan Raya Bekasi Km. 21 Pulogadung - Jakarta Utara 14250, Indonesia Telephone : 6221 - 4603121 (Hunting) Faximile : 6221 - 4602792 Manufacturing of Sulphuric Acid, Aluminium Sulphate, Oleum, Sodium Silicate, Sulphur Block, etc. M S D S No. 006 – MI – 2008 (SDS Oleum) 1. PRODUCT & COMPANY IDENTIFICATION
 PRODUCT
Jl. Raya Bekasi Km.21. Pulogadung.
Jakarta Utara. 14250 2. HAZARD IDENTIFICATION
GHS CLASSIFICATION
Physical Hazard Classification
Oxidizing Liquid
Health and Environment Hazard Identification
Acute Toxicity
Category 1A ( Health Hazard symbol, Danger ) Category 1A ( Health Hazard symbol, Danger ) (Repeated expoure)Hazardous to the Aquatic Environment Category 1 ( Fish and tree symbol, Warning ) Office & Factory : Jalan Raya Bekasi Km. 21 Pulogadung - Jakarta Utara 14250, Indonesia Telephone : 6221 - 4603121 (Hunting) Faximile : 6221 - 4602792 Manufacturing of Sulphuric Acid, Aluminium Sulphate, Oleum, Sodium Silicate, Sulphur Block, etc. M S D S No. 006 – MI – 2008 (SDS Oleum) GHS LABEL ELEMENT
HAZARD STATEMENTS
Human Effect :
HAZARD STATEMENT
 Extremely corrosive, causes serious burns  Harmful by inhalation, ingestion, and through skin contact  Skin contact can lead extensive and severe burns May cause respiratory irritation  Chronic exposure may result in lung damage, possibly cancer and lung damage  Cause damage to organs (nervous system, respiratory system) through prolonged or PRECAUTIONARY STATEMENT
 Wear respiratory protection, protective glove/clothing/face protection as specified by manufacturer/supplier or the competent authority  Wear eye protection ( chemichal goggles )  Protective clothing or contaminated work clothing should not be allowed out of the  Do not eat, drink or smoke when using this product  Do not handle until all safety precaution have been read and understood.
 This substance may be hazardous to the environment, special attention should be Office & Factory : Jalan Raya Bekasi Km. 21 Pulogadung - Jakarta Utara 14250, Indonesia Telephone : 6221 - 4603121 (Hunting) Faximile : 6221 - 4602792 Manufacturing of Sulphuric Acid, Aluminium Sulphate, Oleum, Sodium Silicate, Sulphur Block, etc. M S D S No. 006 – MI – 2008 (SDS Oleum) 3. COMPOSITION / INFORMATION ON INGREDIENTS
Fuming Sulphuric Acid, Pyrosulphuric Acid,Disulphuric Acid, Sulphuric Acid, Mixture withsulphure trioxide.
Ingredient
Percent WT
4. FIRST-AID MEASURE
 Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. Ifbreathing is difficult, give oxygen. Do not use mouth to mouth. If breathing hasceased apply artificial respiration using oxygen and suitable mechanichal devicesuch as bag and a mask.
 Ingestion
Do not induce vomiting. If victim conscious and alert, give 2 – 4 cupfull of milk or water. Never give anything by mouth to an unconscious person. Get medical aidimmediately.
 Skin Contact :
If skin or hair contact, immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothingbefore reuse. Destroy contaminated shoes.
 Eye Contact :
Get medical aid immediately. Do not allow victim to rub or keep eyes closed.
Extensive irritation with water is required ( at least 30 minutes ).
Office & Factory : Jalan Raya Bekasi Km. 21 Pulogadung - Jakarta Utara 14250, Indonesia Telephone : 6221 - 4603121 (Hunting) Faximile : 6221 - 4602792 Manufacturing of Sulphuric Acid, Aluminium Sulphate, Oleum, Sodium Silicate, Sulphur Block, etc. M S D S No. 006 – MI – 2008 (SDS Oleum) 5. FIRE-FIGTHING MEASURES
 Fire and explosion Hazard
Not flammable but highly reactive. Strong dehydrating agent, which may causeignition of finely divided combustible materials on contact. Reacts violently withwater with evolution of heat can react with organic materials explosively. Reactwith most metal , organic materials, nitrates, carbides, chlorates especially whendilute to give flammable potentially explosive hydrogen gas.
 Fire Fighting Advice
Generates heat upon addition of water, with possible splattering and violentliberation of heat. Run off from fire control may cause pollution, neutralize run offwith lime, soda ash, etc prevent corrosion of metal and formation of hydrogen gas.
Strong oxidizer, contact with combustible material may cause fire. Wear selfcontained breathing apparatus if fumes or mist are present.
 Suitable Extinguishing Media
Do not use water directly on fire. Use carbondioxyde or dry chemichal. Do not get water inside containers. Contact professional fire fighters immediately.Coolcontainers with flooding quantities of water until well after fire is out.
6. ACCIDENTAL RELEASE MEASURES
 Personal Precautions
Wear protective equipment to prevent skin, eye contact and respiratory  Methods for cleaning up
Avoid runn off into storm sewers and ditches which lead to waterways.
Clean up spill immediately., observing precautions in the protectiveequipment section. Provide ventilation. Use waterways to reduce vapors, donot put water directly on leak, spill area or inside container. Cover with dryearth, dry sand or other non combustible material followed with plastic sheetto minimize spreading and contact with water. Keep combustibles ( wood,paper, oil and etc ) away from spilled material.
Office & Factory : Jalan Raya Bekasi Km. 21 Pulogadung - Jakarta Utara 14250, Indonesia Telephone : 6221 - 4603121 (Hunting) Faximile : 6221 - 4602792 Manufacturing of Sulphuric Acid, Aluminium Sulphate, Oleum, Sodium Silicate, Sulphur Block, etc. M S D S No. 006 – MI – 2008 (SDS Oleum) 7. HANDLING AND STORAGE
 Handling
Avoid skin and e ye contact and breathing. Keep from contact with moist air andsteam. Carbon steel storage tanks must be vented.
 Storage Color Code
 Storage Advice
Store in cool place, dry place and out of direct sunlight. Store away fromincompatible materials described. Keep containers closed when not in use-check regularly for spills. Keep away from water. Corrosive area. Do notstore near alkaline substances. Store protected from moisture. Metal and ,specifically carbon steel, storage tanks must be vented due to hydrogenreleased.
8. EXPOSURE CONTROL/PERSONAL PROTECTION
 ENGINEERING MEASURES
Facilities storing or utilizing this material should be equipped with an eyewashfacility and a safety shower. Use only under a chemichal fume hood.
 CONTROL PARAMETERS
Office & Factory : Jalan Raya Bekasi Km. 21 Pulogadung - Jakarta Utara 14250, Indonesia Telephone : 6221 - 4603121 (Hunting) Faximile : 6221 - 4602792 Manufacturing of Sulphuric Acid, Aluminium Sulphate, Oleum, Sodium Silicate, Sulphur Block, etc. M S D S No. 006 – MI – 2008 (SDS Oleum)  PERSONAL PROTECTIVE EQUIPMENT
Avoid generating and inhaling always wear respirator when necessary.
Wear safety glasses with side shields or chemichal goggles and a fullface shield.
Suitable wear acid-resistant apron and safety shoes.
9. PHYSICAL AND CHEMICAL PROPERTIES
: Miscible in all proportions in water, react violently with  Evaporation Rate (BuAc = 1 ) : Not applicable 10. STABILITY & REACTIVITY
 Chemichal Stability
Combines vigorously with water with evolution of heat. Reported to haveexploded when in sealed container. This was most likely due to pressure ofhydrogen by reducing of water. Stable under normal ambient conditionstemperature and pressure.
 Hazardous Decomposition Products :
May includes oxide of sulphur ( Sulphur trioxide, Sulphur dioxide and Sulphuricacid vapours) , irritating and toxic fumes and gases  Incompatibilities with other material :
Incompatible with bases, strong dehydrating agents, organic materials, finelypowdered metals, moisture, carbides, chlorates, cyanides, azides, fulminates,picrates, nitrates, alkali halides, zinc, iodide, permanganates, hydrogen peroxides,perchlorates, nitromethane, phosporus, nitrites, cyclopentadiene, lithium silicades,benzene, reducing agents.
Office & Factory : Jalan Raya Bekasi Km. 21 Pulogadung - Jakarta Utara 14250, Indonesia Telephone : 6221 - 4603121 (Hunting) Faximile : 6221 - 4602792 Manufacturing of Sulphuric Acid, Aluminium Sulphate, Oleum, Sodium Silicate, Sulphur Block, etc. M S D S No. 006 – MI – 2008 (SDS Oleum)  Conditions to Avoid
Incompatibles materials, ignition sources, metals, excess heat, combustiblematerials, organic materials, reducing agents, exposure to koist air or wate,oxidizers, amines, bases.
11. TOXICOLOGICAL INFORMATION
 Acute Toxicity :
Sulphuric Acid
 Cancer List
ECOLOGICAL INFORMATION
Environmental Fate
Avoid contamining waterways. Dissociates in water to form sulfate salts,especially with calcium and magnesium.
Ecotoxicity
Office & Factory : Jalan Raya Bekasi Km. 21 Pulogadung - Jakarta Utara 14250, Indonesia Telephone : 6221 - 4603121 (Hunting) Faximile : 6221 - 4602792 Manufacturing of Sulphuric Acid, Aluminium Sulphate, Oleum, Sodium Silicate, Sulphur Block, etc. M S D S No. 006 – MI – 2008 (SDS Oleum) DISPOSAL CONSIDERATION
Spill/ Leak Procedures
Spill procedures are dictated by site Refer to water waste Management Authority.
Large and small spill
Sweep and shovel up dryer chemichal and placed in covered container. Dike with inert material ( sand, earth etc ) and neutralize with soda ash and lime. Anhydroussodium sulphate is useful to treat spills of oleum. Adequate ventilate must beprovided.
Clean up
Wash impacted areas with plenty of water or inert material to remove residues.
TRANSPORT INFORMATION
 The UN classification number
 Air Transport
Not classified as Dangerous Goods by the criteria of International Air TransportAssociation ( IATA ) Dangerous Regulations for transport by air  Any transportation practice must be in compliance with laws and regulation in Office & Factory : Jalan Raya Bekasi Km. 21 Pulogadung - Jakarta Utara 14250, Indonesia Telephone : 6221 - 4603121 (Hunting) Faximile : 6221 - 4602792 Manufacturing of Sulphuric Acid, Aluminium Sulphate, Oleum, Sodium Silicate, Sulphur Block, etc. M S D S No. 006 – MI – 2008 (SDS Oleum) 15. REGULATORY INFORMATION
EINECS : Listed (no. 231-639-5)Classification & Labeling (67/548/EEC) : R20/21/22 – Harmful by inhalation, in contact with skin and if R36/37/38 - Irritating to eyes, respiratory systems and skin.
S2 - Keep out of the reach of children.
S36/37/39 - Wear suitable protective clothing, gloves and eye 16. OTHER INFORMATION
1) Data generated by PT. Mahkota Indonesia2) Guidebook for GH S Classification and Labelling, March, 3) Purple Book Rev 2, 20074) UNRTDG Orange Books 14th edition5) Dangerous Properties of Material 6th edition, N. Irving Sach, 6) Hazardous Material in Industry 12th edition  To the best of our knowledge, the information contained here in is accurate. However, neither PT. MAHKOTA INDONESIA nor any of its subsidiaries assumes any liabilitywhat so ever for the accuracy or completeness of the information contained herein. Finaldetermination of suitability of any material. All materials may present unknown hazardsand should be used with caution. Although certain hazards are described herein, wecannot guarantee that these are the only hazards which exist.

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